Tetranuclear dysprosium single-molecule magnets: tunable magnetic interactions and magnetization dynamics through modifying coordination number

Coordination-perturbed single-molecule magnet behaviour of mononuclear dysprosium complexes.

By changing the ratio of reactants, two mononuclear Dy complexes, [Dy(phen)(acac)(3)] (1) and [Dy(phen)(2)(NO(3))(2)(acac)]·H(2)O (2) have been synthesized and structurally characterized. In 1, a Dy atom bearing square-antiprism coordination geometry exhibits SMM behaviour, while compound 2 with a bicapped-square-antiprism geometry does not show such SMM properties. The different magnetic behav...

Magnetization process of single molecule magnets at low temperatures.

We show that correlations established before quenching to very low temperatures later drive the magnetization process of systems of single molecule magnets, after a magnetic field is applied at t=0. We also show that in simple cubic lattices m proportional, variant sqrt[t], as observed in Fe8, but only for 1+2log((10)(h(d)/h(w)) time decades, where h(d) is a nearest neighbor dipolar magnetic fi...

Photon-induced magnetization changes in single-molecule magnets „invited..

Microwave radiation applied to single-molecule magnets can induce large magnetization changes when the radiation is resonant with transitions between spin levels. These changes are interpreted as due to resonant heating of the sample by the microwaves. Pulsed-radiation studies show that the magnetization continues to decrease after the radiation has been turned off with a rate that is consisten...

Tunneling, remanence, and frustration in dysprosium-based endohedral single-molecule magnets

Single-Molecule Magnets

Single-molecule magnets (SMMs) continue to be an attractive research field because of their unique and intriguing properties and potential applications in high-density data storage technologies and molecular spintronics. The anisotropic barrier (U) of an SMM is derived from a combination of an appreciable spin ground state (S) and uniaxial Ising-like magneto-anisotropy (D). The magnet-like beha...